Glover-Humphreys, William (2026) Establishing the Structure–Environment–Property Relationship of Shape Persistence & Conformationally Dynamic Chiral Redox-Active Aromatic Diimide Macrocycles. PhD thesis, University of York.
Metadata
| Supervisors: | Avestro, Alyssa-Jennifer |
|---|---|
| Keywords: | ADI = Aromatic diimide, ADA = Aromatic dianhydride, CB[n] = Cucurbit[n]uril, CD = Circular dichroism, COSY = Correlation spectroscopy, CPP = Cycloparaphenylene, CPPs = Cycloparaphenylenes, CV = Cyclic voltammetry, DFT =Density functional theory, DPV = Differential pulse voltammetry, ESI = Electrospray ionisation, EXSY = Exchange spectroscopy, HMBC = Heteronuclear multiple bond correlation, HOMO = Highest occupied molecular orbital, HOF = Hydrogen-Bonded organic framework, HSQC = Heteronuclear single quantum coherence, LUMO = Lowest unoccupied molecular orbital, NCI = Non-Covalent interaction, NDA = Naphthalene dianhydride, NDI = Naphthalene diimide, NMR = Nuclear magnetic resonance, NOESY = Nuclear overhauser effect spectroscopy, PDA = Perylene tetracarboxylic dianhydride, PDI = Perylene diimide, PMDA = Pyromellitic dianhydride, PMDI = Pyromellitic diimide, TFA = Trifluoroacetic acid, THF = Tetrahydrofuran, DCM or CH2Cl2 = Dichloromethane DMSO = Dimethyl sulfoxide, MeCN = Acetonitrile, CHCl3 = Chloroform, DBE = 1,2-Dibromoethane, TCE = 1,1,2,2-Tetrachloroethane, DMF = N, N-Dimethylformamide, TLC = Thin-Layer chromatography, UV-vis Ultraviolet–Visible spectroscopy, VT = Variable temperature, XRD = X-ray diffraction, RDG = Reduced density gradient, I3− = Triiodide anion, 2NDI = Dimeric naphthalene diimide macrocycle, 3NDI = Trimeric naphthalene diimide molecular triangle, 4NDI = Tetrameric naphthalene diimide macrocycle, 3PDI = Trimeric perylene diimide molecular triangle, 3PMDI also 6H = Trimeric pyromellitic diimide molecular triangle, 4PMDI = Tetrameric pyromellitic diimide macrocycle, 6PMDI = Hexameric pyromellitic diimide macrocycle, 2PMDINDI =Mixed two pyromellitic diimide one naphthalene diimide based molecular triangle, 2NDIPMDI = Mixed two naphthalene diimide one pyromellitic diimide based molecular triangle, 2NDIPMDIBr = Mixed two naphthalene diimide one mono brominated pyromellitic diimide based molecular triangle, 1Br =Mono-brominated three pyromellitic diimide based molecular triangle, 2Br = Di-brominated three pyromellitic diimide based molecular triangle, 3Br = Tri-brominated three pyromellitic diimide based molecular triangle, 6Br = Hexa-brominated three pyromellitic diimide based molecular triangle, (3PMDI)2 = Dimer of trimeric pyromellitic diimide molecular triangles, (2NDIPMDI)2 = Dimer of a mixed two naphthalene diimide one pyromellitic diimide based molecular triangles, (PMDI)2 = Covalently coupled pyromellitic diimide dimer, (3PMDI)2-PMDI = Trimeric Pyromellitic diimide molecular triangle covalently coupled to a single pyromellitic diimide, (3PMDI)2–(PMDI)2 = Trimeric pyromellitic diimide molecular triangle covalently coupled to two pyromellitic diimide, (2NDIPMDI)–PMDI = Mixed two naphthalene diimide one pyromellitic diimide based molecular triangles covalently coupled to a single pyromellitic diimide, |
| Awarding institution: | University of York |
| Academic Units: | The University of York > Chemistry (York) |
| Date Deposited: | 26 Oct 2026 11:49 |
| Last Modified: | 26 Oct 2026 11:49 |
| Open Archives Initiative ID (OAI ID): | oai:etheses.whiterose.ac.uk:39401 |
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