data_rob382afi_mo
_audit_creation_date              2013-07-23
_audit_creation_method
;
  Olex2 1.2
  (compiled Apr 23 2013 17:59:47, GUI svn.r4466)
;
_publ_contact_author_address      ?
_publ_contact_author_email        ?
_publ_contact_author_name         ''
_publ_contact_author_phone        ?
_chemical_name_common             ?
_chemical_name_systematic         ?
_chemical_formula_moiety          'C14 H24 Cl2 N Rh'
_chemical_formula_sum             'C14 H24 Cl2 N Rh'
_chemical_formula_weight          380.15
_chemical_absolute_configuration  ad
_chemical_melting_point           ?
loop_
  _atom_type_symbol
  _atom_type_description
  _atom_type_scat_dispersion_real
  _atom_type_scat_dispersion_imag
  _atom_type_scat_source
 'C' 'C' 0.0033 0.0016 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'H' 'H' 0.0000 0.0000 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Cl' 'Cl' 0.1484 0.1585 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'N' 'N' 0.0061 0.0033 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'
 'Rh' 'Rh' -1.1178 0.9187
 'International Tables Vol C Tables 4.2.6.8 and 6.1.1.4'

_space_group_crystal_system       'orthorhombic'
_space_group_IT_number            29
_space_group_name_H-M_alt         'P c a 21'
_space_group_name_Hall            'P 2c -2ac'
loop_
  _space_group_symop_id
  _space_group_symop_operation_xyz
 1 'x, y, z'
 2 '-x, -y, z+1/2'
 3 '-x+1/2, y, z+1/2'
 4 'x+1/2, -y, z'

_cell_length_a                    14.4171(7)
_cell_length_b                    8.4571(4)
_cell_length_c                    25.4892(11)
_cell_angle_alpha                 90.00
_cell_angle_beta                  90.00
_cell_angle_gamma                 90.00
_cell_volume                      3107.8(2)
_cell_formula_units_Z             8
_cell_measurement_reflns_used     3963
_cell_measurement_temperature     100.01(10)
_cell_measurement_theta_max       29.3060
_cell_measurement_theta_min       2.8080
_exptl_absorpt_coefficient_mu     1.426
_exptl_absorpt_correction_T_max   1.00000
_exptl_absorpt_correction_T_min   0.79445
_exptl_absorpt_correction_type    multi-scan
_exptl_absorpt_process_details
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28e (release 10-06-2013 CrysAlis171 .NET)
(compiled Jun 10 2013,11:58:50)
Empirical absorption correction using spherical harmonics,
 implemented in SCALE3 ABSPACK scaling algorithm.
;
_exptl_crystal_colour             orange
_exptl_crystal_colour_primary     orange
_exptl_crystal_density_diffrn     1.625
_exptl_crystal_density_meas       ?
_exptl_crystal_density_method     'not measured'
_exptl_crystal_description        block
_exptl_crystal_F_000              1552
_exptl_crystal_recrystallization_method 'crystallised from DCM and Hexane'
_exptl_crystal_size_max           0.18
_exptl_crystal_size_mid           0.14
_exptl_crystal_size_min           0.07
_exptl_special_details
;
 ? 
;
_diffrn_reflns_av_R_equivalents   0.0399
_diffrn_reflns_av_unetI/netI      0.0574
_diffrn_reflns_limit_h_max        16
_diffrn_reflns_limit_h_min        -18
_diffrn_reflns_limit_k_max        8
_diffrn_reflns_limit_k_min        -11
_diffrn_reflns_limit_l_max        32
_diffrn_reflns_limit_l_min        -34
_diffrn_reflns_number             11665
_diffrn_reflns_theta_full         25.00
_diffrn_reflns_theta_max          29.73
_diffrn_reflns_theta_min          2.41
_diffrn_ambient_temperature       100.01(10)
_diffrn_detector_area_resol_mean  5.3095
_diffrn_measured_fraction_theta_full 0.9983
_diffrn_measured_fraction_theta_max 0.6765
_diffrn_measurement_details
;
#__ type_ start__ end____ width___ exp.time_
  1 omega  -58.00   -5.00   1.0000   20.0000
omega____ theta____ kappa____ phi______ frames
    -        9.1407  -57.0000 -150.0000 53

#__ type_ start__ end____ width___ exp.time_
  2 omega  -14.00   38.00   1.0000   20.0000
omega____ theta____ kappa____ phi______ frames
    -        9.1407  -77.0000  -30.0000 52

#__ type_ start__ end____ width___ exp.time_
  3 omega  -13.00   19.00   1.0000   20.0000
omega____ theta____ kappa____ phi______ frames
    -       -9.9220  -99.0000  -30.0000 32
;
_diffrn_measurement_device_type   'SuperNova, Dual, Cu at zero, Atlas'
_diffrn_measurement_method        '\w scans'
_diffrn_orient_matrix_UB_11       -0.0259852000
_diffrn_orient_matrix_UB_12       0.0408357000
_diffrn_orient_matrix_UB_13       0.0193621000
_diffrn_orient_matrix_UB_21       0.0263021000
_diffrn_orient_matrix_UB_22       0.0693523000
_diffrn_orient_matrix_UB_23       -0.0047578000
_diffrn_orient_matrix_UB_31       -0.0324260000
_diffrn_orient_matrix_UB_32       0.0236605000
_diffrn_orient_matrix_UB_33       -0.0194210000
_diffrn_radiation_monochromator   mirror
_diffrn_radiation_type            'Mo K\a'
_diffrn_radiation_wavelength      0.7107
_diffrn_source                    'SuperNova (Mo) X-ray Source'
_diffrn_standards_decay_%         ?
_diffrn_standards_interval_count  ?
_diffrn_standards_interval_time   ?
_diffrn_standards_number          ?
_reflns_number_gt                 5526
_reflns_number_total              6035
_reflns_odcompleteness_completeness 99.83
_reflns_odcompleteness_iscentric  1
_reflns_odcompleteness_theta      26.32
_reflns_threshold_expression      >2sigma(I)
_computing_cell_refinement
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28e (release 10-06-2013 CrysAlis171 .NET)
(compiled Jun 10 2013,11:58:50)
;
_computing_data_collection
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28e (release 10-06-2013 CrysAlis171 .NET)
(compiled Jun 10 2013,11:58:50)
;
_computing_data_reduction
;
CrysAlisPro, Agilent Technologies,
Version 1.171.36.28e (release 10-06-2013 CrysAlis171 .NET)
(compiled Jun 10 2013,11:58:50)
;
_computing_molecular_graphics
;
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
;
_computing_publication_material
;
O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard and H. Puschmann,
OLEX2: a complete structure solution, refinement and analysis program.
J. Appl. Cryst. (2009). 42, 339-341.
;
_computing_structure_refinement
;
SHELXL, G.M. Sheldrick, Acta Cryst.
(2008). A64, 112-122
;
_computing_structure_solution
;
SHELXS, G.M. Sheldrick, Acta Cryst.
(2008). A64, 112-122
;
_refine_diff_density_max          0.464
_refine_diff_density_min          -0.566
_refine_diff_density_rms          0.111
_refine_ls_abs_structure_details  'Flack H D (1983), Acta Cryst. A39, 876-881'
_refine_ls_abs_structure_Flack    -0.07(3)
_refine_ls_extinction_coef        ?
_refine_ls_extinction_method      none
_refine_ls_goodness_of_fit_ref    1.044
_refine_ls_hydrogen_treatment     riding
_refine_ls_matrix_type            full
_refine_ls_number_parameters      337
_refine_ls_number_reflns          6035
_refine_ls_number_restraints      1
_refine_ls_R_factor_all           0.0390
_refine_ls_R_factor_gt            0.0341
_refine_ls_restrained_S_all       1.044
_refine_ls_shift/su_max           0.001
_refine_ls_shift/su_mean          0.000
_refine_ls_structure_factor_coef  Fsqd
_refine_ls_weighting_details
'calc w=1/[\s^2^(Fo^2^)+(0.0234P)^2^+0.0000P] where P=(Fo^2^+2Fc^2^)/3'
_refine_ls_weighting_scheme       calc
_refine_ls_wR_factor_gt           0.0698
_refine_ls_wR_factor_ref          0.0725
_refine_special_details
;
 Refinement of F^2^ against ALL reflections.  The weighted R-factor wR and 
 goodness of fit S are based on F^2^, conventional R-factors R are based 
 on F, with F set to zero for negative F^2^. The threshold expression of 
 F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is 
 not relevant to the choice of reflections for refinement.  R-factors based 
 on F^2^ are statistically about twice as large as those based on F, and R- 
 factors based on ALL data will be even larger. 
;
_olex2_refinement_description
;
1. Fixed Uiso
 At 1.2 times of:
  All C(H,H) groups
 At 1.5 times of:
  All C(H,H,H) groups
2.a Secondary CH2 refined with riding coordinates:
 C3(H3A,H3B), C17(H17A,H17B), C4(H4A,H4B), C18(H18A,H18B), C19(H19A,H19B),
 C5(H5A,H5B)
2.b Idealised Me refined as rotating group:
 C2(H2A,H2B,H2C), C16(H16A,H16B,H16C), C1(H1A,H1B,H1C), C14(H14A,H14B,H14C),
 C25(H25A,H25B,H25C), C26(H26A,H26B,H26C), C13(H13A,H13B,H13C), C15(H15A,H15B,
 H15C), C12(H12A,H12B,H12C), C28(H28A,H28B,H28C), C11(H11A,H11B,H11C), C27(H27A,
 H27B,H27C)
;
_atom_sites_solution_hydrogens    geom
_atom_sites_solution_primary      direct
_atom_sites_solution_secondary    difmap
loop_
  _atom_site_label
  _atom_site_type_symbol
  _atom_site_fract_x
  _atom_site_fract_y
  _atom_site_fract_z
  _atom_site_U_iso_or_equiv
  _atom_site_adp_type
  _atom_site_occupancy
  _atom_site_symmetry_multiplicity
  _atom_site_calc_flag
  _atom_site_refinement_flags
  _atom_site_disorder_assembly
  _atom_site_disorder_group
 Rh1 Rh 0.63992(2) 0.60530(4) 0.250530(12) 0.01009(8) Uani 1 1 d . . .
 Rh2 Rh 0.57233(2) 0.10826(4) 0.496540(12) 0.00962(8) Uani 1 1 d . . .
 Cl3 Cl 0.45796(9) 0.12921(13) 0.56571(5) 0.0144(2) Uani 1 1 d . . .
 Cl1 Cl 0.75260(9) 0.61669(13) 0.18042(5) 0.0151(2) Uani 1 1 d . . .
 Cl2 Cl 0.70456(9) 0.35905(14) 0.28239(5) 0.0162(3) Uani 1 1 d . . .
 Cl6 Cl 0.50537(9) -0.13714(14) 0.46604(5) 0.0149(2) Uani 1 1 d . . .
 C7 C 0.6380(4) 0.8582(5) 0.2537(3) 0.0167(11) Uani 1 1 d . . .
 C24 C 0.5791(4) 0.3620(5) 0.4911(3) 0.0190(12) Uani 1 1 d . . .
 C9 C 0.6423(4) 0.7051(6) 0.3288(2) 0.0156(11) Uani 1 1 d . . .
 N1 N 0.5450(3) 0.4707(5) 0.20009(15) 0.0134(8) Uani 1 1 d . . .
 N2 N 0.6644(3) -0.0262(4) 0.54880(15) 0.0115(8) Uani 1 1 d . . .
 C2 C 0.5931(4) 0.3771(6) 0.1587(2) 0.0174(11) Uani 1 1 d . . .
 H2A H 0.6390 0.3104 0.1746 0.026 Uiso 1 1 calc R . .
 H2B H 0.6226 0.4477 0.1343 0.026 Uiso 1 1 calc R . .
 H2C H 0.5487 0.3130 0.1404 0.026 Uiso 1 1 calc R . .
 C16 C 0.6129(4) -0.1163(6) 0.5898(2) 0.0178(11) Uani 1 1 d . . .
 H16A H 0.5648 -0.1775 0.5735 0.027 Uiso 1 1 calc R . .
 H16B H 0.5859 -0.0437 0.6144 0.027 Uiso 1 1 calc R . .
 H16C H 0.6550 -0.1855 0.6078 0.027 Uiso 1 1 calc R . .
 C22 C 0.5715(3) 0.2027(6) 0.41709(19) 0.0146(11) Uani 1 1 d . . .
 C1 C 0.4914(4) 0.3562(6) 0.2315(2) 0.0174(11) Uani 1 1 d . . .
 H1A H 0.4585 0.4111 0.2587 0.026 Uiso 1 1 calc R . .
 H1B H 0.5329 0.2806 0.2470 0.026 Uiso 1 1 calc R . .
 H1C H 0.4479 0.3023 0.2093 0.026 Uiso 1 1 calc R . .
 C14 C 0.4691(4) 0.6334(6) 0.3388(2) 0.0222(12) Uani 1 1 d . . .
 H14A H 0.4839 0.5272 0.3491 0.033 Uiso 1 1 calc R . .
 H14B H 0.4156 0.6326 0.3164 0.033 Uiso 1 1 calc R . .
 H14C H 0.4563 0.6957 0.3694 0.033 Uiso 1 1 calc R . .
 C25 C 0.7443(4) 0.1225(6) 0.4089(2) 0.0223(13) Uani 1 1 d . . .
 H25A H 0.7304 0.0136 0.4018 0.033 Uiso 1 1 calc R . .
 H25B H 0.7986 0.1288 0.4307 0.033 Uiso 1 1 calc R . .
 H25C H 0.7555 0.1771 0.3765 0.033 Uiso 1 1 calc R . .
 C26 C 0.5394(4) 0.1182(6) 0.36858(19) 0.0211(12) Uani 1 1 d . . .
 H26A H 0.4736 0.1015 0.3705 0.032 Uiso 1 1 calc R . .
 H26B H 0.5703 0.0180 0.3660 0.032 Uiso 1 1 calc R . .
 H26C H 0.5536 0.1810 0.3383 0.032 Uiso 1 1 calc R . .
 C3 C 0.4802(4) 0.5810(6) 0.17202(19) 0.0148(11) Uani 1 1 d . . .
 H3A H 0.4415 0.5183 0.1489 0.018 Uiso 1 1 calc R . .
 H3B H 0.5172 0.6504 0.1501 0.018 Uiso 1 1 calc R . .
 C21 C 0.6651(4) 0.1964(6) 0.43642(19) 0.0173(11) Uani 1 1 d . . .
 C13 C 0.6743(4) 0.6251(6) 0.3787(2) 0.0228(12) Uani 1 1 d . . .
 H13A H 0.7404 0.6111 0.3776 0.034 Uiso 1 1 calc R . .
 H13B H 0.6447 0.5238 0.3819 0.034 Uiso 1 1 calc R . .
 H13C H 0.6582 0.6896 0.4084 0.034 Uiso 1 1 calc R . .
 C10 C 0.5494(4) 0.7032(6) 0.3100(2) 0.0160(11) Uani 1 1 d . . .
 C15 C 0.7193(4) -0.1438(6) 0.5181(2) 0.0190(11) Uani 1 1 d . . .
 H15A H 0.7504 -0.0913 0.4897 0.028 Uiso 1 1 calc R . .
 H15B H 0.6785 -0.2233 0.5043 0.028 Uiso 1 1 calc R . .
 H15C H 0.7644 -0.1927 0.5406 0.028 Uiso 1 1 calc R . .
 C6 C 0.5464(4) 0.7982(5) 0.26294(18) 0.0163(11) Uani 1 1 d . . .
 C17 C 0.7285(4) 0.0855(6) 0.5768(2) 0.0185(12) Uani 1 1 d . . .
 H17A H 0.7650 0.0247 0.6016 0.022 Uiso 1 1 calc R . .
 H17B H 0.6910 0.1589 0.5969 0.022 Uiso 1 1 calc R . .
 C12 C 0.7994(4) 0.8335(6) 0.2998(2) 0.0226(12) Uani 1 1 d . . .
 H12A H 0.8287 0.8276 0.2660 0.034 Uiso 1 1 calc R . .
 H12B H 0.8274 0.7579 0.3230 0.034 Uiso 1 1 calc R . .
 H12C H 0.8071 0.9379 0.3139 0.034 Uiso 1 1 calc R . .
 C23 C 0.5165(4) 0.2999(6) 0.45076(19) 0.0168(11) Uani 1 1 d . . .
 C20 C 0.6679(4) 0.2982(6) 0.48286(18) 0.0163(11) Uani 1 1 d . . .
 C4 C 0.4176(4) 0.6824(6) 0.2051(2) 0.0212(12) Uani 1 1 d . . .
 H4A H 0.3927 0.6177 0.2332 0.025 Uiso 1 1 calc R . .
 H4B H 0.3658 0.7164 0.1836 0.025 Uiso 1 1 calc R . .
 C28 C 0.5482(4) 0.4797(6) 0.5313(2) 0.0241(13) Uani 1 1 d . . .
 H28A H 0.5944 0.4882 0.5583 0.036 Uiso 1 1 calc R . .
 H28B H 0.4907 0.4456 0.5465 0.036 Uiso 1 1 calc R . .
 H28C H 0.5397 0.5809 0.5149 0.036 Uiso 1 1 calc R . .
 C8 C 0.6981(4) 0.7977(6) 0.29427(18) 0.0149(11) Uani 1 1 d . . .
 C18 C 0.7948(4) 0.1808(6) 0.5432(2) 0.0240(13) Uani 1 1 d . . .
 H18A H 0.8201 0.1118 0.5164 0.029 Uiso 1 1 calc R . .
 H18B H 0.8459 0.2156 0.5650 0.029 Uiso 1 1 calc R . .
 C11 C 0.6678(4) 0.9693(6) 0.2109(2) 0.0254(13) Uani 1 1 d . . .
 H11A H 0.6248 0.9630 0.1822 0.038 Uiso 1 1 calc R . .
 H11B H 0.7286 0.9403 0.1989 0.038 Uiso 1 1 calc R . .
 H11C H 0.6691 1.0754 0.2242 0.038 Uiso 1 1 calc R . .
 C27 C 0.4160(4) 0.3371(6) 0.4458(2) 0.0230(12) Uani 1 1 d . . .
 H27A H 0.3883 0.3398 0.4801 0.035 Uiso 1 1 calc R . .
 H27B H 0.3863 0.2572 0.4250 0.035 Uiso 1 1 calc R . .
 H27C H 0.4087 0.4382 0.4292 0.035 Uiso 1 1 calc R . .
 C19 C 0.7522(4) 0.3271(6) 0.5161(2) 0.0227(12) Uani 1 1 d . . .
 H19A H 0.7361 0.4034 0.5430 0.027 Uiso 1 1 calc R . .
 H19B H 0.7995 0.3749 0.4941 0.027 Uiso 1 1 calc R . .
 C5 C 0.4630(4) 0.8298(6) 0.2295(2) 0.0236(12) Uani 1 1 d . . .
 H5A H 0.4809 0.9008 0.2014 0.028 Uiso 1 1 calc R . .
 H5B H 0.4170 0.8840 0.2507 0.028 Uiso 1 1 calc R . .

loop_
  _atom_site_aniso_label
  _atom_site_aniso_U_11
  _atom_site_aniso_U_22
  _atom_site_aniso_U_33
  _atom_site_aniso_U_23
  _atom_site_aniso_U_13
  _atom_site_aniso_U_12
 Rh1 0.01139(18) 0.00951(16) 0.00936(16) 0.0003(2) 0.00068(14) -0.00039(14)
 Rh2 0.01125(18) 0.00877(16) 0.00885(16) 0.0010(2) 0.00012(15) 0.00033(14)
 Cl3 0.0138(6) 0.0152(5) 0.0143(5) -0.0008(5) 0.0035(5) 0.0000(5)
 Cl1 0.0138(6) 0.0158(5) 0.0156(5) 0.0005(5) 0.0048(5) -0.0013(5)
 Cl2 0.0167(7) 0.0142(5) 0.0177(6) 0.0039(5) -0.0018(5) 0.0013(5)
 Cl6 0.0162(6) 0.0132(5) 0.0153(6) -0.0021(5) -0.0015(5) -0.0014(5)
 C7 0.021(3) 0.013(2) 0.016(3) -0.010(3) 0.003(2) 0.001(2)
 C24 0.037(3) 0.006(2) 0.013(3) 0.001(3) 0.008(2) -0.005(2)
 C9 0.022(3) 0.014(3) 0.010(2) -0.003(2) 0.001(2) 0.000(2)
 N1 0.012(2) 0.016(2) 0.0118(19) 0.0040(18) 0.0014(17) 0.0016(17)
 N2 0.013(2) 0.0121(19) 0.0093(18) -0.0002(17) -0.0030(16) 0.0019(17)
 C2 0.019(3) 0.020(3) 0.014(2) -0.001(2) -0.002(2) 0.000(2)
 C16 0.017(3) 0.020(3) 0.017(3) 0.012(2) 0.003(2) 0.002(2)
 C22 0.021(3) 0.014(3) 0.009(2) 0.004(2) 0.0015(19) 0.002(2)
 C1 0.016(3) 0.017(2) 0.019(3) 0.001(2) -0.002(2) -0.005(2)
 C14 0.020(3) 0.031(3) 0.016(3) -0.011(2) 0.004(2) -0.001(3)
 C25 0.018(3) 0.029(3) 0.020(3) 0.005(2) 0.005(2) 0.002(2)
 C26 0.027(3) 0.025(3) 0.012(2) 0.000(2) -0.001(2) 0.003(2)
 C3 0.016(3) 0.018(2) 0.010(2) 0.001(2) -0.002(2) -0.002(2)
 C21 0.021(3) 0.017(3) 0.014(2) 0.007(2) 0.003(2) -0.001(2)
 C13 0.029(3) 0.027(3) 0.013(2) 0.000(2) -0.001(2) -0.007(3)
 C10 0.017(3) 0.013(2) 0.018(2) -0.004(2) 0.006(2) -0.002(2)
 C15 0.018(3) 0.020(2) 0.019(2) 0.002(2) -0.003(2) 0.004(2)
 C6 0.023(3) 0.010(2) 0.016(3) -0.003(2) 0.003(2) 0.010(2)
 C17 0.018(3) 0.022(3) 0.016(3) 0.000(2) -0.003(2) 0.002(2)
 C12 0.027(3) 0.019(3) 0.021(3) -0.005(2) 0.005(2) -0.008(2)
 C23 0.020(3) 0.015(2) 0.016(2) 0.010(2) 0.002(2) 0.001(2)
 C20 0.018(3) 0.014(2) 0.017(3) 0.004(2) 0.002(2) -0.002(2)
 C4 0.012(3) 0.031(3) 0.021(3) -0.004(2) -0.006(2) 0.004(2)
 C28 0.038(4) 0.013(3) 0.021(3) 0.001(2) 0.009(3) -0.002(2)
 C8 0.017(3) 0.018(2) 0.010(2) -0.006(2) 0.004(2) -0.004(2)
 C18 0.023(3) 0.027(3) 0.022(3) -0.010(2) -0.002(2) -0.008(3)
 C11 0.045(4) 0.009(2) 0.023(3) 0.003(2) 0.006(3) 0.002(2)
 C27 0.025(3) 0.028(3) 0.017(2) 0.007(2) 0.003(2) 0.012(3)
 C19 0.025(3) 0.023(3) 0.019(3) -0.003(2) 0.002(2) -0.011(2)
 C5 0.020(3) 0.017(3) 0.033(3) 0.000(3) 0.002(2) 0.007(2)

_geom_special_details
;
 All esds (except the esd in the dihedral angle between two l.s. planes) 
 are estimated using the full covariance matrix.  The cell esds are taken 
 into account individually in the estimation of esds in distances, angles 
 and torsion angles; correlations between esds in cell parameters are only 
 used when they are defined by crystal symmetry.  An approximate (isotropic) 
 treatment of cell esds is used for estimating esds involving l.s. planes. 
;
loop_
  _geom_bond_atom_site_label_1
  _geom_bond_atom_site_label_2
  _geom_bond_distance
  _geom_bond_site_symmetry_2
  _geom_bond_publ_flag
 Rh1 Cl1 2.4170(12) . ?
 Rh1 Cl2 2.4219(12) . ?
 Rh1 C7 2.141(5) . ?
 Rh1 C9 2.166(5) . ?
 Rh1 N1 2.195(4) . ?
 Rh1 C10 2.164(5) . ?
 Rh1 C6 2.140(5) . ?
 Rh1 C8 2.144(5) . ?
 Rh2 Cl3 2.4204(12) . ?
 Rh2 Cl6 2.4173(12) . ?
 Rh2 C24 2.153(5) . ?
 Rh2 N2 2.198(4) . ?
 Rh2 C22 2.177(5) . ?
 Rh2 C21 2.166(5) . ?
 Rh2 C23 2.153(5) . ?
 Rh2 C20 2.145(5) . ?
 C7 C6 1.434(7) . ?
 C7 C8 1.444(8) . ?
 C7 C11 1.503(8) . ?
 C24 C23 1.467(8) . ?
 C24 C20 1.404(7) . ?
 C24 C28 1.496(8) . ?
 C9 C13 1.514(7) . ?
 C9 C10 1.422(7) . ?
 C9 C8 1.427(7) . ?
 N1 C2 1.491(6) . ?
 N1 C1 1.476(6) . ?
 N1 C3 1.502(6) . ?
 N2 C16 1.491(6) . ?
 N2 C15 1.493(6) . ?
 N2 C17 1.502(6) . ?
 C22 C26 1.501(7) . ?
 C22 C21 1.437(7) . ?
 C22 C23 1.429(7) . ?
 C14 C10 1.492(7) . ?
 C25 C21 1.479(8) . ?
 C3 C4 1.503(7) . ?
 C21 C20 1.464(7) . ?
 C10 C6 1.443(7) . ?
 C6 C5 1.497(8) . ?
 C17 C18 1.515(7) . ?
 C12 C8 1.498(7) . ?
 C23 C27 1.487(7) . ?
 C20 C19 1.502(7) . ?
 C4 C5 1.540(7) . ?
 C18 C19 1.544(7) . ?

loop_
  _geom_angle_atom_site_label_1
  _geom_angle_atom_site_label_2
  _geom_angle_atom_site_label_3
  _geom_angle
  _geom_angle_site_symmetry_1
  _geom_angle_site_symmetry_3
  _geom_angle_publ_flag
 Cl1 Rh1 Cl2 91.35(4) . . ?
 C7 Rh1 Cl1 89.81(17) . . ?
 C7 Rh1 Cl2 148.40(18) . . ?
 C7 Rh1 C9 64.9(2) . . ?
 C7 Rh1 N1 122.1(2) . . ?
 C7 Rh1 C10 65.4(2) . . ?
 C7 Rh1 C8 39.4(2) . . ?
 C9 Rh1 Cl1 130.90(14) . . ?
 C9 Rh1 Cl2 91.16(14) . . ?
 C9 Rh1 N1 138.68(17) . . ?
 N1 Rh1 Cl1 90.37(11) . . ?
 N1 Rh1 Cl2 89.45(11) . . ?
 C10 Rh1 Cl1 155.18(14) . . ?
 C10 Rh1 Cl2 109.05(14) . . ?
 C10 Rh1 C9 38.35(19) . . ?
 C10 Rh1 N1 103.45(17) . . ?
 C6 Rh1 Cl1 120.16(14) . . ?
 C6 Rh1 Cl2 148.05(13) . . ?
 C6 Rh1 C7 39.14(19) . . ?
 C6 Rh1 C9 64.96(19) . . ?
 C6 Rh1 N1 95.12(18) . . ?
 C6 Rh1 C10 39.19(18) . . ?
 C6 Rh1 C8 65.9(2) . . ?
 C8 Rh1 Cl1 95.23(13) . . ?
 C8 Rh1 Cl2 109.13(14) . . ?
 C8 Rh1 C9 38.66(18) . . ?
 C8 Rh1 N1 160.41(17) . . ?
 C8 Rh1 C10 65.27(19) . . ?
 Cl6 Rh2 Cl3 91.43(4) . . ?
 C24 Rh2 Cl3 90.29(16) . . ?
 C24 Rh2 Cl6 148.58(18) . . ?
 C24 Rh2 N2 121.8(2) . . ?
 C24 Rh2 C22 64.8(2) . . ?
 C24 Rh2 C21 65.4(2) . . ?
 C24 Rh2 C23 39.8(2) . . ?
 N2 Rh2 Cl3 90.45(11) . . ?
 N2 Rh2 Cl6 89.55(11) . . ?
 C22 Rh2 Cl3 130.33(13) . . ?
 C22 Rh2 Cl6 90.78(14) . . ?
 C22 Rh2 N2 139.19(17) . . ?
 C21 Rh2 Cl3 155.59(15) . . ?
 C21 Rh2 Cl6 108.33(14) . . ?
 C21 Rh2 N2 103.54(18) . . ?
 C21 Rh2 C22 38.63(19) . . ?
 C23 Rh2 Cl3 94.86(14) . . ?
 C23 Rh2 Cl6 108.81(14) . . ?
 C23 Rh2 N2 160.70(17) . . ?
 C23 Rh2 C22 38.54(18) . . ?
 C23 Rh2 C21 65.69(19) . . ?
 C20 Rh2 Cl3 120.08(13) . . ?
 C20 Rh2 Cl6 147.91(13) . . ?
 C20 Rh2 C24 38.15(19) . . ?
 C20 Rh2 N2 95.62(17) . . ?
 C20 Rh2 C22 65.01(19) . . ?
 C20 Rh2 C21 39.70(18) . . ?
 C20 Rh2 C23 65.70(19) . . ?
 C6 C7 Rh1 70.4(3) . . ?
 C6 C7 C8 108.0(5) . . ?
 C6 C7 C11 127.2(6) . . ?
 C8 C7 Rh1 70.4(3) . . ?
 C8 C7 C11 124.7(5) . . ?
 C11 C7 Rh1 126.4(4) . . ?
 C23 C24 Rh2 70.1(3) . . ?
 C23 C24 C28 122.3(5) . . ?
 C20 C24 Rh2 70.6(3) . . ?
 C20 C24 C23 108.6(5) . . ?
 C20 C24 C28 129.0(5) . . ?
 C28 C24 Rh2 127.3(4) . . ?
 C13 C9 Rh1 127.2(4) . . ?
 C10 C9 Rh1 70.7(3) . . ?
 C10 C9 C13 124.5(5) . . ?
 C10 C9 C8 109.2(4) . . ?
 C8 C9 Rh1 69.8(3) . . ?
 C8 C9 C13 126.3(5) . . ?
 C2 N1 Rh1 113.6(3) . . ?
 C2 N1 C3 106.4(4) . . ?
 C1 N1 Rh1 110.4(3) . . ?
 C1 N1 C2 106.2(4) . . ?
 C1 N1 C3 109.9(4) . . ?
 C3 N1 Rh1 110.2(3) . . ?
 C16 N2 Rh2 112.9(3) . . ?
 C16 N2 C15 106.9(4) . . ?
 C16 N2 C17 107.1(4) . . ?
 C15 N2 Rh2 110.4(3) . . ?
 C15 N2 C17 110.0(4) . . ?
 C17 N2 Rh2 109.6(3) . . ?
 C26 C22 Rh2 126.4(4) . . ?
 C21 C22 Rh2 70.3(3) . . ?
 C21 C22 C26 123.7(5) . . ?
 C23 C22 Rh2 69.8(3) . . ?
 C23 C22 C26 126.6(5) . . ?
 C23 C22 C21 109.7(4) . . ?
 N1 C3 C4 117.4(4) . . ?
 C22 C21 Rh2 71.1(3) . . ?
 C22 C21 C25 125.3(5) . . ?
 C22 C21 C20 106.4(5) . . ?
 C25 C21 Rh2 131.8(4) . . ?
 C20 C21 Rh2 69.4(3) . . ?
 C20 C21 C25 127.6(5) . . ?
 C9 C10 Rh1 70.9(3) . . ?
 C9 C10 C14 124.6(5) . . ?
 C9 C10 C6 107.6(5) . . ?
 C14 C10 Rh1 131.4(4) . . ?
 C6 C10 Rh1 69.5(3) . . ?
 C6 C10 C14 127.3(5) . . ?
 C7 C6 Rh1 70.4(3) . . ?
 C7 C6 C10 107.8(5) . . ?
 C7 C6 C5 125.6(5) . . ?
 C10 C6 Rh1 71.3(3) . . ?
 C10 C6 C5 126.6(5) . . ?
 C5 C6 Rh1 123.9(3) . . ?
 N2 C17 C18 117.0(4) . . ?
 C24 C23 Rh2 70.1(3) . . ?
 C24 C23 C27 125.7(5) . . ?
 C22 C23 Rh2 71.6(3) . . ?
 C22 C23 C24 106.6(4) . . ?
 C22 C23 C27 127.7(5) . . ?
 C27 C23 Rh2 124.7(3) . . ?
 C24 C20 Rh2 71.2(3) . . ?
 C24 C20 C21 108.8(5) . . ?
 C24 C20 C19 126.2(5) . . ?
 C21 C20 Rh2 70.9(3) . . ?
 C21 C20 C19 125.0(5) . . ?
 C19 C20 Rh2 123.4(3) . . ?
 C3 C4 C5 115.7(4) . . ?
 C7 C8 Rh1 70.2(3) . . ?
 C7 C8 C12 125.6(4) . . ?
 C9 C8 Rh1 71.5(3) . . ?
 C9 C8 C7 107.3(4) . . ?
 C9 C8 C12 127.1(4) . . ?
 C12 C8 Rh1 125.7(3) . . ?
 C17 C18 C19 115.4(5) . . ?
 C20 C19 C18 116.3(4) . . ?
 C6 C5 C4 115.3(4) . . ?